Abstract: |
Increased applied interest to the fabrication of geometrical and optical patterns, photonic crystals and other elements of photonics stimulated our investigations on new functional light-sensitive materials and development of holographic methods for optical recording of two- and three-dimensional optical elements. In contrast to the number of known multi-step lithography, nanoimprint processes, we have developed the method of single-step recording of photonic crystals based on four-beam interference. This method was adjusted to the recording in acrylate nanocomposites and enabled the simple change of the periods and depth profiles of the resulting structures. Special polymer nanocomposites, based on acrylates and silica nanoparticles were used in this method. Enhancement of phase modulation due to the polymerization of the monomer matrix and redistribution of nanoparticles occurs in this media. Further enhancement of the recording parameters, changes of the polymerization processes and of the profile formation was realised in these nanocomposites due to the addition of gold nanoparticles, like it was published in [1,2]. AFM, SEM and micro-Raman profilings were used to establish the structure of the recorded photonic crystals. The role of the plasmon fields of the selectively excited gold nanoparticles with given dimensions in the recording process was investigated with aim to use optimum combination of matrix polymer, initiator and laser excitation parameters.
This work was supported by Ministry of Education of Russian Federation project № 3.432.2014/K.
References
1. J. Burunkova, I. Csarnovics, I. Denisyuk, L. Daróczi, S. Kökényesi, Journal of Non-Crystalline Solids 402 (2014) 200–203
2. J. Burunkova , S. Kokenyesi, I. Csarnovics , A. Bonyár , M. Veres, A. Csik, European Polymer Journal 64 (2015) 189–195.
|